Snehasis Jana, Mahendra Kumar Trivedi, Rama Mohan Tallapragada, Alice Branton, Gopal Nayak, Rakesh Kumar Mishra

Chitosan (CS) and sodium alginate (SA) are two widely popular biopolymers which are used for biomedical and pharmaceutical applications from many years. The objective of present study was to study the effect of biofield treatment on physical, chemical and thermal properties of CS and SA. The study was performed in two groups (control and treated). The control group remained as untreated, and biofield treatment was given to treated group. The control and treated polymers were characterized by Fourier transform infrared (FT-IR) spectroscopy, CHNSO analysis, X-ray diffraction (XRD), particle size analysis, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). FT-IR of treated chitosan showed increase in frequency of –CH stretching (2925→2979 cm-1) vibrations with respect to control. However, the treated SA showed increase in frequency of –OH stretching (3182→3284 cm-1) which may be correlated to increase in force constant or bond strength with respect to control. CHNSO results showed significant increase in percentage of oxygen and hydrogen of treated polymers (CS and SA) with respect to control. XRD studies revealed that crystallinity was improved in treated CS as compared to control. The percentage crystallite size was increased significantly by 69.59% in treated CS with respect to control. However, treated SA showed decrease in crystallite size by 41.04% as compared to control sample. The treated SA showed significant reduction in particle size (d50 and d99) with respect to control SA. DSC study showed changes in decomposition temperature in treated CS with respect to control. A significant change in enthalpy was observed in treated polymers (CS and CA) with respect to control. TGA results of treated CS showed decrease in Tmax with respect to control. Likewise, the treated SA also showed decrease in Tmax which could be correlated to reduction in thermal stability after biofield treatment. Overall, the results showed that biofield treatment has significantly changed the physical, chemical and thermal properties of CS and SA.

Mahendra Kumar Trivedi, Alice Branton, Gopal Nayak, Gunin Saikia, Snehasis Jana

The objective of the present study was to evaluate the impact of biofield energy treatment on the thermal, spectroscopic, and chemical properties of anisole by various analytical methods such as gas chromatography-mass spectrometry (GC-MS), high performance liquid chromatography (HPLC), differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) spectroscopy, and ultraviolet-visible (UV-Vis) spectroscopy. The anisole sample was divided into two parts, control and treated. The control part was remained same while the other part was treated with Mr. Trivedi’s unique biofield energy treatment. Mass spectra showed the molecular ion peak with five fragmented peaks in control and all treated samples. The isotopic abundance ratio of 2H/1H, and 13C/12C [(PM+1)/PM] in treated sample was increased by 154.47% (T1) as compared to the control [where, PM- primary molecule, (PM+1)-isotopic molecule either for 13C or 2H]. The HPLC chromatogram showed retention time of treated anisole was slightly decreased as compared to the control. Moreover, the heat change in the sharp endothermic transition of treated anisole was increased by 389.07% in DSC thermogram as compared to the control. Further, C-C aromatic stretching frequency of treated sample was shifted by 2 cm-1 to low energy region in FT-IR spectroscopy. The UV-Vis spectra of control sample showed characteristic absorption peaks at 325 nm, which was red shifted and appeared as shoulder in the treated sample. These results suggested that biofield treatment has significantly altered the physical and spectroscopic properties of anisole, which could make them stable solvent for organic synthesis and as a suitable reaction intermediate in industrial applications.

Snehasis Jana, Mahendra Kumar Trivedi, Rama Mohan Tallapragada, Alice Branton, Gopal Nayak, Rakesh Kumar Mishra

O-aminophenol has extensive uses as a conducting material and in electrochemical devices. The objective of this research was to investigate the influence of biofield energy treatment on the physical thermal and spectral properties of o-aminophenol. The study was performed in two groups; the control group was remained as untreated, while the treated group was subjected to Mr. Trivedi’s biofield energy treatment. Subsequently, the control and treated o-aminophenol samples were characterized by X-ray diffraction (XRD), Differential scanning calorimetry (DSC), Thermogravimetric analysis (TGA), surface area analysis, Fourier transform infrared (FT-IR) spectroscopy, and Ultra violet-visible spectroscopy analysis (UV-vis). The XRD analysis showed an increase in peak intensity of the treated o-aminophenol with respect to the control. Additionally, the crystallite size of the treated o-aminophenol was increased by 34.51% with respect to the control sample. DSC analysis showed a slight increase in the melting temperature of the treated sample as compared to the control. However, a significant increase in the latent heat of fusion was observed in the treated o-aminophenol by 162.24% with respect to the control. TGA analysis showed an increase in the maximum thermal decomposition temperature (Tmax) in treated o-aminophenol (178.17ºC) with respect to the control (175ºC). It may be inferred that the thermal stability of o-aminophenol increased after the biofield treatment. The surface area analysis using BET showed a substantial decrease in the surface area of the treated sample by 47.1% as compared to the control. The FT-IR analysis showed no changes in the absorption peaks of the treated sample with respect to the control. UV-visible analysis showed alteration in the absorption peaks i.e. 211→203 nm and 271→244 nm of the treated o-aminophenol as compared to the control. Overall, the results showed that the biofield treatment caused an alteration in the physical, thermal and spectral properties of the treated o-aminophenol.

Mahendra Kumar Trivedi, Alice Branton, Gopal Nayak, Ragini Singh, Snehasis Jana

The chloronitrobenzenes are widely used as the intermediates in the production of pharmaceuticals, pesticides and rubber processing chemicals. However, due to their wide applications, they are frequently released into the environment thereby creating hazards. The objective of the study was to use an alternative strategy i.e. biofield energy treatment and analysed its impact on the physical, thermal and spectral properties of 3-chloronitrobenzene (3-CNB). For the study, the 3-CNB sample was taken and divided into two groups, named as control and treated. The analytical techniques used were X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), UV-Visible (UV-Vis), and Fourier transform infrared (FT-IR) spectroscopy. The treated group was subjected to the biofield energy treatment and analysed using these techniques against the control sample. The XRD data showed an alteration in relative intensity of the peak along with 30% decrease in the crystallite size of the treated sample as compared to the control. The TGA studies revealed the decrease in onset temperature of degradation from 140ºC (control) to 120°C, while maximum thermal degradation temperature was changed from 157.61ºC (control) to 150.37ºC in the treated sample as compared to the control. Moreover, the DSC studies revealed the decrease in the melting temperature from 51°C (control) →47°C in the treated sample. Besides, the UV-Vis and FT-IR spectra of the treated sample did not show any significant alteration in terms of wavelength and frequencies of the peaks, respectively from the control sample. The overall study results showed the impact of biofield energy treatment on the physical and thermal properties of 3-CNB that can further affect its use as a chemical intermediate and its fate in the environment.